Steam Methane Reformer, Natural Gas Reforming Hydrogen Production

Most hydrogen produced today in China is made via steam-methane reforming, a mature production process in which high-temperature steam (**0°C*1,**0°C) is used to produce hydrogen from a methane source, such as natural gas. In steam-methane reforming, methane reacts with steam under ***5 bar pressure (1 bar = *4.5 psi) in the presence of a catalyst to produce hydrogen, carbon monoxide, and a relatively small amount of carbon dioxide. Steam reforming is endothermic-that is, heat must be supplied to the process for the reaction to proceed.

Subsequently, in what is called the "water-gas shift reaction," the carbon monoxide and steam are reacted using a catalyst to produce carbon dioxide and more hydrogen. In a final process step called "pressure-swing adsorption," carbon dioxide and other impurities are removed from the gas stream, leaving essentially pure hydrogen. Steam reforming can also be used to produce hydrogen from other fuels, such as ethanol, propane, or even gasoline.

Steam-methane reforming reaction
CH4 + H2O (+ heat) → CO + 3H2

Water-gas shift reaction
CO + H2O → CO2 + H2 (+ small amount of heat)